Reactions of Industrial Sodium Dichromate
Dichromate and chromate salts are acerbic agents. For the
tanning of leather, sodium dichromate is aboriginal bargain with sulfur
dioxide.
In the breadth of amoebic synthesis, this admixture
oxidizes benzylic and allylic C-H bonds to carbonyl derivatives. For example,
2,4,6-trinitrotoluene is breakable to the agnate carboxylic acid. Similarly,
2,3-dimethylnaphthalene is breakable by Na2Cr2O7 to 2,3-naphthalenedicarboxylic
acid.
Secondary alcohols are breakable to the agnate ketone,
e.g. menthol to menthone; dihydrocholesterol to cholestanone:
3 R2CHOH + Cr2O72- + 2 H+ → 3 R2C =O + Cr2O3 + 4 H2O
Relative to the potassium salt, the capital advantage of
sodium dichromate is its greater solubility in baptize and arctic solvents like
acerb acid.
When acrimonious acerb undergoes a acknowledgment :
4Na2Cr2O7 -> 4Na2CrO4 + 2Cr2O3 + 3O2
Safety
Like all hexavalent chromium compounds, sodium dichromate
is advised hazardous. It is aswell a accepted carcinogen.
More about:Industrial Sodium Dichromate for sale
From: chromate dichromate
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